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Season 1, episode 16

Polluting by Computer
Dr Blight and Sly Sludge hack into government computers and reclassify America's nature reserves as toxic waste dumps. And, as if that wasn't enough, they also make it look as though THEY are the eco-warriors and the Planeteers are the ones engaged in illegal pollution.
Release date: 23 February 1991
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Captain Planet and the Planeteers