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Season 1, episode 23

Mission to Save Earth (2)
Now with Commander Clash on their side, the Planeteers convince him to use his powers to serve and protect the environment, and to help them recover their rings from the eco-villains by using technology to create synthetic versions of their powers. With Captain Pollution on a rampage, can Captain Planet be summoned in time?
Release date: 11 May 1991
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Captain Planet and the Planeteers