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Season 5, episode 1

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Twilight Ozone
While studying the effects of ozone depletion, the Planeteers encounter scientists in the Australian Outback who are experimenting on new life forms that thrive on deadly levels of UV radiation. And when their prize specimen, Duke Nukem, goes on a radioactive rampage, the Planeteers are forced to give him the slip, slap, slop!
Release date: 10 September 1994
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Captain Planet and the Planeteers