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Season 1, episode 10

TV or Not TV
Brain develops a special pair of dentures that can produce a smile that can hypnotize anyone who is not wearing a special pair of sunglasses. In order to take over the world, he needs people to see the mesmerizing smile. He figures that he needs to get on TV and in order to do that he has to become a celebrity.
Release date: 19 November 1995
Network:
Pinky and the Brain